Electrochemistry Quiz
Grade 11 · Science · Quiz
10 questions covering oxidation-reduction, galvanic cells, electrolysis, standard potentials, and Faraday's Laws.
Questions
What does 'oxidation' mean in terms of electrons?
- Gain of electrons
- Loss of electrons
- Transfer of protons
- Addition of oxygen only
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Answer: Loss of electrons
OIL — Oxidation Is Loss (of electrons). The oxidation number increases when electrons are lost.
In a galvanic cell, at which electrode does reduction occur?
- Anode
- Cathode
- Salt bridge
- Both electrodes equally
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Answer: Cathode
RIG — Reduction Is Gain. Electrons flow from anode to cathode; at the cathode they are gained by the oxidizing agent.
Calculate E°cell: E°cathode = +1.36 V, E°anode = +0.34 V.
- +1.70 V
- +1.02 V
- +0.68 V
- −1.02 V
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Answer: +1.02 V
E°cell = E°cathode − E°anode = 1.36 − 0.34 = +1.02 V.
What indicates a spontaneous electrochemical reaction?
- Negative E°cell
- Zero E°cell
- Positive E°cell
- High temperature only
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Answer: Positive E°cell
A positive E°cell corresponds to a negative ΔG (ΔG = −nFE°cell), confirming the reaction is thermodynamically spontaneous.
What process occurs at the anode during electrolysis?
- Reduction
- Deposition of metal
- Oxidation
- Proton transfer
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Answer: Oxidation
Oxidation always occurs at the anode — in electrolytic cells the anode is connected to the positive terminal, attracting anions that lose electrons.
In Zn + CuSO₄ → ZnSO₄ + Cu, copper is:
- Oxidized and is the reducing agent
- Reduced and is the oxidizing agent
- Oxidized and is the oxidizing agent
- Neither oxidized nor reduced
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Answer: Reduced and is the oxidizing agent
Cu²⁺ gains 2 electrons → Cu (reduction). By accepting electrons, Cu²⁺ oxidizes zinc — making it the oxidizing agent.
Electroplating uses which type of cell?
- Galvanic cell
- Fuel cell
- Electrolytic cell
- Concentration cell
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Answer: Electrolytic cell
Electroplating is a nonspontaneous process requiring electrical energy — it uses an electrolytic cell with the object to be plated as the cathode.
Faraday's Laws of electrolysis state that the mass of substance deposited is proportional to:
- Voltage applied
- Temperature of the solution
- Charge passed (current × time)
- Concentration of electrolyte
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Answer: Charge passed (current × time)
Q = It (charge = current × time). Mass deposited ∝ Q ∝ moles of electrons transferred.
The standard hydrogen electrode (SHE) has a standard reduction potential of:
- +1.00 V
- +0.50 V
- 0.00 V
- −1.00 V
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Answer: 0.00 V
The SHE (2H⁺ + 2e⁻ → H₂) is assigned exactly 0.00 V and serves as the universal reference for all standard reduction potentials.
Zinc coated on steel (galvanizing) prevents rusting because:
- Zinc blocks oxygen from reaching the steel
- Zinc has a lower reduction potential than iron and preferentially oxidizes
- Zinc is nonreactive with water
- Zinc acts as a cathode
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Answer: Zinc has a lower reduction potential than iron and preferentially oxidizes
Zinc (E° = −0.76 V) is more easily oxidized than iron (E° = −0.44 V). It acts as a sacrificial anode, corroding in place of the steel.
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